202252 - How do you like your hydrogen sulphide? Rotten eggs over easy?
A routine transfer of bilge water from the engine room bilges to the bilge water tank was being undertaken. During the transfer, the crew detected a smell of rotten eggs from the bilge tank vent, an indicator of hydrogen sulphide (H2S) gas. The transfer was immediately stopped so that an investigation could determine more facts. Using a multi-gas detector, measurements at the tank vent pipe indicated H2S at a level of 453ppm.
Immediate preventive actions were taken to ensure the H2S fumes would not enter the accommodation. Ducting was installed from the tank vent to the ship’s side to ventilate the tank and continuous monitoring of the area near the tank vent was undertaken until gas concentration readings were reduced to safe levels.
Seawater in bilge tanks, and in particular engine room bilges, mixed with other residues and bio-degradable detergents created conditions favourable for the formation of dangerous levels of H2S gas.
How dangerous is H2S?
Very! The pictogram below found on the referenced Safety Alert gives an excellent idea of the consequences. Even 10 ppm is acceptable only if exposure is restricted to eight hours per day.
Anything at or above 320 ppm is dangerous or lethal and cannot be detected by smell.
Any indication of the presence of H2S should be taken with the greatest urgency